Title : Analysis of site-specific glycosylation in recombinant human
follistatin expressed in Chinese hamster ovary cells
Abstract :
- Follistatin (FS) FS ), a glycoprotein , plays an important role in cell growth and differentiation through the neutralization of the biological activities of activins
- In this study, we analyzed the glycosylation of recombinant human FS ( rhFS ) produced in Chinese hamster ovary cells
- The results of SDS-PAGE and MALDI-TOF MS revealed the presence of both non-glycosylated and glycosylated forms
- FS contains two potential N-glycosylation sites, Asn95 and Asn259
- Using mass spectrometric peptide/glycopeptide mapping and precursor-ion scanning, we found that both N-glycosylation sites were partially glycosylated
- Monosaccharide com position analyses suggested the linkages of fucosylated bi- and triantennary complex-type oligosaccharides on rhFS
- This finding was supported by mass spectrometric oligosaccharide profiling, in which the m/z values and elution times of some of the oligosaccharides from rhFS were in good agreement with those of standard oligosaccharides
- Site-specific glycosylation was deduced on the basis of the mass spectra of the glycopeptides
- It was suggested that biantennary oligosaccharides are major oligosaccharides located at both Asn95 and Asn259 , whereas the triantennary structures are present mainly at Asn95
Output (sent_index, trigger,
protein,
sugar,
site):
- 0. glycosylation, , follistatin, -, -
- 1. glycoprotein, , Follistatin (FS), -, -
- 1. glycoprotein, , glycoprotein, -, -
- 2. glycosylation, , rhFS, -, -
- 4. N-glycosylation, , -, -, sites, Asn95 and Asn259
- 5. N-glycosylation, , -, -, sites
- 5. glycosylated, , -, -, sites
- 5. peptide/glycopeptide, , -, -, peptide/glycopeptide
- 6. fucosylated, , -, fucosylated bi- and triantennary complex-type oligosaccharides, -
- 7. rhFS, , rhFS, the oligosaccharides, -
- 8. glycopeptides, , -, -, glycopeptides
- 9. present, , -, the triantennary structures, Asn95
Output(Part-Of) (sent_index,
protein,
site):
- 4. FS, sites, Asn95 and Asn259
*Output_Site_Fusion* (sent_index,
protein,
sugar,
site):
- 4. FS, -, sites, Asn95 and Asn259
- 9. follistatin, the triantennary structures, Asn95