Title : Hinge-Region O-Glycosylation of
Human Immunoglobulin G3 (
IgG3 )
Abstract :
- Immunoglobulin G ( IgG ) is one of the most abundant proteins present in human serum and a fundamental component of the immune system
- IgG3 represents ∼8% of the total amount of IgG in human serum and stands out from the other IgG subclasses because of its elongated hinge region and enhanced effector functions
- This study reports partial O-glycosylation of the IgG3 hinge region , observed with nanoLC- ESI-IT-MS(/MS) analysis after proteolytic digestion
- The repeat regions within the IgG3 hinge were found to be in part O-glycosylated at the threonine in the triple repeat motif
- Non-, mono- and disialylated core 1-type O-glycans were detected in various IgG3 samples, both poly- and monoclonal
- NanoLC- ESI-IT-MS/MS with electron transfer dissociation fragmentation and CE-MS/MS with CID fragmentation were used to determine the site of IgG3 O-glycosylation
- The O-glycosylation site was further confirmed by the recombinant production of mutant IgG3 in which potential O-glycosylation sites had been knocked out
- For IgG3 samples from six donors we found similar O-glycan structures and site occupancies, whereas for the same samples the conserved N-glycosylation of the Fc CH2 domain showed considerable interindividual variation
- The occupancy of each of the three O-glycosylation sites was found to be ∼10% in six serum-derived IgG3 samples and ∼13% in two monoclonal IgG3 allotypes
Output (sent_index, trigger,
protein,
sugar,
site):
- 0. O-Glycosylation, , Human Immunoglobulin G3, -, -
- 0. O-Glycosylation, , IgG3, -, -
- 3. O-glycosylation, , -, -, region
- 4. O-glycosylated, , -, -, -
- 4. O-glycosylated, , -, -, threonine
- 4. threonine, , -, The repeat regions, threonine
- 4. threonine, , -, the triple repeat motif, threonine
- 6. O-glycosylation, , -, -, site
- 7. O-glycosylation, , -, -, site
- 7. O-glycosylation, , -, -, sites
- 8. N-glycosylation, , -, -, domain
- 9. O-glycosylation, , -, -, sites
- 9. occupancy, , -, -, sites
Output(Part-Of) (sent_index,
protein,
site):
*Output_Site_Fusion* (sent_index,
protein,
sugar,
site):